Issue 12, 2003
From the journal:

Journal of Materials Chemistry

Aerosol-assisted metallo-organic chemical vapour deposition of Bi2Se3 films using single-molecule precursors. The crystal structure of bismuth(iii) dibutyldiselenocarbamate

Olinda C. Monteiro,a   Tito Trindade,*a   Filipe A. Almeida Paz,b   Jacek Klinowski,b   John Watersc  and  Paul O'Brienc  

* Corresponding authors

a Department of Chemistry, CICECO, University of Aveiro, Aveiro, Portugal
E-mail: ttrindade@dq.ua.pt
Fax: +351-234-370084
Tel: +351-234-370726

b Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, UK

c The Manchester Materials Science Centre, Department of Chemistry, University of Manchester, Oxford Road, Manchester, UK

Abstract

The complexes [Bi{Se2CN(C2H5)2}3], [Bi{Se2CN(C4H9)2}3], [Bi{Se2CN(CH3)(C4H9)}3] and [Bi{Se2CN(CH3)(C6H13)}3] have been synthesized and characterized structurally using IR, 1H and 13C NMR. In addition, the crystal structure of [Bi{Se2CN(C4H9)2}3] was determined by single-crystal X-ray diffraction, showing the bismuth centre coordinated to three dialkyldiselenocarbamate ligands through the selenium donor atoms. The Bi(III) compounds were used as precursors for the deposition of Bi2Se3 films on glass substrates through aerosol-assisted metallo-organic chemical vapour deposition (AA-MOCVD).

Graphical abstract: Aerosol-assisted metallo-organic chemical vapour deposition of Bi2Se3 films using single-molecule precursors. The crystal structure of bismuth(iii) dibutyldiselenocarbamate

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Article information

DOI
https://doi.org/10.1039/B306662M
Article type
Paper
Submitted
11 Jun 2003
Accepted
07 Oct 2003
First published
24 Oct 2003

J. Mater. Chem., 2003,13, 3006-3010

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Aerosol-assisted metallo-organic chemical vapour deposition of Bi2Se3 films using single-molecule precursors. The crystal structure of bismuth(III) dibutyldiselenocarbamate

O. C. Monteiro, T. Trindade, F. A. A. Paz, J. Klinowski, J. Waters and P. O'Brien, J. Mater. Chem., 2003, 13, 3006 DOI: 10.1039/B306662M

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