Synthesis and structure determination of reduced tantalates, Li2LaTa2O7, Li2Ca2Ta3O10 and Na2Ca2Ta3O10, with a layered perovskite structure

Abstract

New reduced tantalates, Li ₂ LaTa ₂ O ₇ , Li ₂ Ca ₂ Ta ₃ O ₁₀ and Na ₂ Ca ₂ Ta ₃ O ₁₀ , with a layered perovskite structure have been synthesized by a chemical or an electrochemical intercalation reaction of the alkali metal cations with the parent Dion-Jacobson series compounds. The crystal structures of these compounds were determined by Rietveld analysis of powder X-ray diffraction patterns, and found to be analogous to those of the parent compounds. The intercalation of the lithium ion leads to a large contraction along the stacking direction of perovskite layers because of a higher interlayer charge density. These intercalation compounds are the first example of reduced tantalates with a layered perovskite structure.