Issue 7, 1998
From the journal:

Journal of Chemical Research, Synopses

Synthesis of Oligo-enynes Using [Fe(alkene)(CO)n] Scaffolds. Z/E-Selective Wittig- and Horner-type Olefination Reactions of η-Carbonyl Groups in η4-Diene and γ-Carbonyl Groups in η2-Alkene Complexes of Iron

Jutta Böhmer  and  Rainer Schobert  

Abstract

β-Oxo-dienetricarbonyliron complexes 4 and γ-oxo-alkenecarbene complexes 5 undergo olefinations with a wide range of phosphonates and phosphoranes with high E- or Z-selectivity and give the free oligo-en(yn)es or carbamates, respectively, upon oxidative demetalation.

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Article information

DOI
https://doi.org/10.1039/A801240G
Article type
Paper

J. Chem. Res. (S), 1998, 372-373

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Synthesis of Oligo-enynes Using [Fe(alkene)(CO)n] Scaffolds. Z/E-Selective Wittig- and Horner-type Olefination Reactions of η-Carbonyl Groups in η4-Diene and γ-Carbonyl Groups in η2-Alkene Complexes of Iron

J. Böhmer and R. Schobert, J. Chem. Res. (S), 1998, 372 DOI: 10.1039/A801240G

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