Issue 0, 1968

Aspects of conformation in ring-substituted 2,4,6-trinitroanilines deduced from absorption spectra

Abstract

From the relative absorption intensities of two characteristic bands in the ultraviolet spectra of 2,4,6-trinitroaniline and its derivatives, it is possible to estimate angles of twist from planarity of the 2-, 4-, and 6-nitro-substituents. In at least one instance, such estimates correspond closely to angles observed in a total crystal structure determination. Other aspects of the spectra are also discussed.

Article information

Article type
Paper

J. Chem. Soc. B, 1968, 1147-1153

Aspects of conformation in ring-substituted 2,4,6-trinitroanilines deduced from absorption spectra

M. J. Kamlet, R. R. Minesinger, J. C. Hoffsommer, J. C. Dacons and H. G. Adolph, J. Chem. Soc. B, 1968, 1147 DOI: 10.1039/J29680001147

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