Mössbauer spectra of some organotin compounds of type R3SnX
Abstract
The Mössbauer spectra of various organotin compounds of formula R3SnX have been recorded. Of particular interest are series of compounds containing tin–metal bonds: (π-C5H5)(CO)3M1–SnMe3(M1= Cr, Mo, W), Me3M2–SnMe3(M2= C, Si, Ge, Sn), Ph3M3–SnPh3(M3= Si, Ge, Sn), Ph3M4–SnMe3(M4= C, Si, Ge, Sn), (Ph3P)2(CO)H(X)Ir–SnPh3(X = Cl, I), (Ph3P)2(CO)Y(Cl)Ir–SnMe3(Y = H, D), (Ph2RP)2(CO)H(Cl)Ir–SnPh3(R = Me, Ph). The results are discussed.