Issue 0, 1971

Covalent compounds of quadrivalent transition metals. Part II. Chromium(IV) tertiary alkoxides and triethylsilyloxide

Abstract

Chromium(IV) tetra-alkoxides Cr(OR)4(R = t-alkyl) and Cr(OSiEt3)4 have been prepared and their reactions studied. Variable-temperature magnetic susceptibilities, electronic and infrared spectra, electron spin resonance, and mass spectra have been measured for Cr(OBut)4 and the results are discussed in terms of a distorted tetrahedral CrO4 unit.

Article information

Article type
Paper

J. Chem. Soc. A, 1971, 772-776

Covalent compounds of quadrivalent transition metals. Part II. Chromium(IV) tertiary alkoxides and triethylsilyloxide

E. C. Alyea, J. S. Basi, D. C. Bradley and M. H. Chisholm, J. Chem. Soc. A, 1971, 772 DOI: 10.1039/J19710000772

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