Issue 0, 1969
From the journal:

Journal of the Chemical Society A: Inorganic, Physical, Theoretical


Oxomolybdenum(IV) complexes

R. N. Jowitt  and  P. C. H. Mitchell  

Abstract

Complexes MoOB2(B = diethyldithiocarbamate, diethyldithiophosphate, or diphenyldithiophosphate) have been prepared by reducing oxomolybdenum(V) complexes, Mo2O3B4, with thiophenol, sodium dithionite, and zinc dust. The complexes are diamagnetic and monomeric. Their n.m.r., i.r., and electronic spectra are reported. The physical measurements indicate square-pyramidal structures. Reduction of the oxinate complex, Mo2O3(C9H6ON)4, gave some MoO(C9H6ON)2 but the acetylacetonate complex, Mo2O3(C3H7O2)4, could not be reduced. It appears that oxomolybdenum(IV) is preferentially stabilised by sulphur-donors.

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Article information

DOI
https://doi.org/10.1039/J19690002632
Article type
Paper

J. Chem. Soc. A, 1969, 2632-2636

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Oxomolybdenum(IV) complexes

R. N. Jowitt and P. C. H. Mitchell, J. Chem. Soc. A, 1969, 2632 DOI: 10.1039/J19690002632

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