The 195Pt and 31P chemical shifts and the platinum–phosphorus coupling constants have been determined for some platinum hydrides trans-[Pt(PEt3)2HL] where L is a series of anionic ligands. The platinum chemical shifts are interpreted in terms of the variation of the paramagnetic shielding term which arises from changes in the σ- and π-covalency of the metal–ligand (L) bond.
R. R. Dean and J. C. Green, J. Chem. Soc. A, 1968, 3047 DOI: 10.1039/J19680003047
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