Issue 0, 1967
From the journal:

Journal of the Chemical Society A: Inorganic, Physical, Theoretical


The interaction of perfluorobutadiene with iron and cobalt carbonyls

R. L. Hunt,   D. M. Roundhill  and  G. Wilkinson  

Abstract

The interactions of perfluorobutadiene with pentacarbonyliron and octacarbonyldicobalt lead, respectively, to the complexes of stoicheiometry C4F6Fe(CO)4 and C4F6Co2(CO)6. The infrared and 19F nuclear magnetic resonance spectra and some chemical properties of the complexes are given. The cobalt complex reacts with triphenyl- and tri-n-butyl-phosphines and triphenylarsine to form paramagnetic adducts, e.g., C4F6Co2(CO)6(AsPh3)2.

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Article information

DOI
https://doi.org/10.1039/J19670000982
Article type
Paper

J. Chem. Soc. A, 1967, 982-984

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The interaction of perfluorobutadiene with iron and cobalt carbonyls

R. L. Hunt, D. M. Roundhill and G. Wilkinson, J. Chem. Soc. A, 1967, 982 DOI: 10.1039/J19670000982

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