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Issue 5, 2017
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Synthesis of (E)-β-iodo vinylsulfones via iodine-promoted iodosulfonylation of alkynes with sodium sulfinates in an aqueous medium at room temperature

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Abstract

An efficient molecular iodine-promoted method for the synthesis of (E)-β-iodo vinylsulfones using water as the solvent at room temperature has been developed. This green reaction is fast, operationally simple, environmentally benign and, especially, proceeds under very mild conditions to afford the target products with high regio- and stereoselectivity.

Graphical abstract: Synthesis of (E)-β-iodo vinylsulfones via iodine-promoted iodosulfonylation of alkynes with sodium sulfinates in an aqueous medium at room temperature

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Publication details

The article was received on 08 Dec 2016, accepted on 23 Jan 2017 and first published on 02 Feb 2017


Article type: Communication
DOI: 10.1039/C6GC03387C
Citation: Green Chem., 2017,19, 1255-1258
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    Synthesis of (E)-β-iodo vinylsulfones via iodine-promoted iodosulfonylation of alkynes with sodium sulfinates in an aqueous medium at room temperature

    Y. Sun, A. Abdukader, D. Lu, H. Zhang and C. Liu, Green Chem., 2017, 19, 1255
    DOI: 10.1039/C6GC03387C

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