Issue 23, 2016

A robust and recyclable polyurea-encapsulated copper(i) chloride for one-pot ring-opening/Huisgen cycloaddition/CO2 capture in water

Abstract

Multicomponent ring-opening/Huisgen cycloaddition reactions combined with CO2 capture with a polyurea-encapsulated copper salt as a catalyst that in situ formed from simple CuCl and soluble polyurea during the reaction were carried out successfully for the synthesis of β-hydroxytriazoles under exceptionally mild conditions, in which the polyurea-encapsulated copper(I) chloride proved to be a robust and recyclable catalyst system with high yields as well as excellent chemoselectivity in this reaction.

Graphical abstract: A robust and recyclable polyurea-encapsulated copper(i) chloride for one-pot ring-opening/Huisgen cycloaddition/CO2 capture in water

Supplementary files

Article information

Article type
Paper
Submitted
18 Jul 2016
Accepted
16 Sep 2016
First published
19 Sep 2016

Green Chem., 2016,18, 6357-6366

A robust and recyclable polyurea-encapsulated copper(I) chloride for one-pot ring-opening/Huisgen cycloaddition/CO2 capture in water

Y. Chen, W. Zhang, B. Yu, Y. Zhao, Z. Gao, Y. Jian and L. Xu, Green Chem., 2016, 18, 6357 DOI: 10.1039/C6GC01956K

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