Issue 6, 2014
From the journal:

Green Chemistry

Direct access to 1,2,3-triazoles through organocatalytic 1,3-dipolar cycloaddition reaction of allyl ketones with azides†

Wenjun Li,ab   Zhiyun Du,*a   Jiayao Huang,b   Qianfa Jia,a   Kun Zhanga  and  Jian Wang*ab  

* Corresponding authors

a Allan H. Conney Laboratory for Anticancer Research, Guangdong University of Technology, Guang Dong, China

b Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543, Singapore
E-mail: chmwangj@nus.edu.sg
Fax: (+) 65-6516-1691

Abstract

A general organocatalytic 1,3-dipolar cycloaddition reaction between allyl ketones and various azides is reported. The reaction is catalyzed by a secondary amine to generate substituted 1,2,3-triazoles with high levels of regioselectivity.

Graphical abstract: Direct access to 1,2,3-triazoles through organocatalytic 1,3-dipolar cycloaddition reaction of allyl ketones with azides

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Article information

DOI
https://doi.org/10.1039/C4GC00406J
Article type
Communication
Submitted
07 Mar 2014
Accepted
27 Mar 2014
First published
01 Apr 2014

Green Chem., 2014,16, 3003-3006

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Direct access to 1,2,3-triazoles through organocatalytic 1,3-dipolar cycloaddition reaction of allyl ketones with azides

W. Li, Z. Du, J. Huang, Q. Jia, K. Zhang and J. Wang, Green Chem., 2014, 16, 3003 DOI: 10.1039/C4GC00406J

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