Issue 2, 2013

Acetal metathesis polymerization (AMP): A method for synthesizing biorenewable polyacetals

Abstract

Polyalkylene acetals are synthesized from simple bio-derived diols and diethoxymethane via a novel technique involving interchange of acetal functional groups. This Acetal Metathesis Polymerization (AMP) method provides a route to polyacetals that are designed to degrade under abiotic conditions via simple acid-catalyzed hydrolysis.

Graphical abstract: Acetal metathesis polymerization (AMP): A method for synthesizing biorenewable polyacetals

Supplementary files

Article information

Article type
Communication
Submitted
09 Oct 2012
Accepted
17 Dec 2012
First published
17 Dec 2012

Green Chem., 2013,15, 325-329

Acetal metathesis polymerization (AMP): A method for synthesizing biorenewable polyacetals

A. G. Pemba, J. A. Flores and S. A. Miller, Green Chem., 2013, 15, 325 DOI: 10.1039/C2GC36588J

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