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Issue 10, 2012
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Pressure-accelerated copper-free cycloaddition of azide and alkyne groups pre-organized in the crystalline state at room temperature

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Abstract

We have designed a supramolecular system to pre-organize the azide and alkyne functional groups via electrostatic and arene–perfluoroarene interactions. After pre-organization, high pressure was applied to accelerate the copper-free cycloaddition of the azide and alkyne groups in the crystalline state.

Graphical abstract: Pressure-accelerated copper-free cycloaddition of azide and alkyne groups pre-organized in the crystalline state at room temperature

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Publication details

The article was received on 11 Jul 2012, accepted on 16 Aug 2012 and first published on 24 Aug 2012


Article type: Communication
DOI: 10.1039/C2GC36069A
Citation: Green Chem., 2012,14, 2703-2705
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    Pressure-accelerated copper-free cycloaddition of azide and alkyne groups pre-organized in the crystalline state at room temperature

    H. Chen, B. Ni, F. Gao and Y. Ma, Green Chem., 2012, 14, 2703
    DOI: 10.1039/C2GC36069A

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