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Issue 7, 2012
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An efficient protocol for palladium-catalyzed ligand-free Suzuki–Miyaura coupling in water

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Abstract

An in situ generated catalytic system based on PdCl2 and sodium sulfate exhibited excellent catalytic activity in the Suzuki–Miyaura cross-coupling reactions of aryl halides with arylboronic acids at room temperature in water. A similar catalytic system can be obtained with PdCl2 and sodium chloride or sodium acetate and is equally effective in Suzuki–Miyaura cross-coupling reactions. This method offers a mild and efficient alternative to the existing protocols since the reaction is proceeded in water at room temperature under ligand free conditions.

Graphical abstract: An efficient protocol for palladium-catalyzed ligand-free Suzuki–Miyaura coupling in water

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Publication details

The article was received on 09 Feb 2012, accepted on 08 May 2012 and first published on 09 May 2012


Article type: Communication
DOI: 10.1039/C2GC35401B
Citation: Green Chem., 2012,14, 1873-1876
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    An efficient protocol for palladium-catalyzed ligand-free Suzuki–Miyaura coupling in water

    M. Mondal and U. Bora, Green Chem., 2012, 14, 1873
    DOI: 10.1039/C2GC35401B

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