Issue 12, 2011
From the journal:

Green Chemistry

Probing the structure-property relationship of regioisomeric ionic liquids with click chemistry†

Hunaid B. Nulwala,*ad   Chau N. Tang,*ab   Brian W. Kail,c   Krishnan Damodaran,a   Palwinder Kaur,a   Shan Wickramanayake,c   Wei Shic  and  David R. Luebke*a  

* Corresponding authors

a National Energy Technology Laboratory, P.O. Box 10940, Pittsburgh, PA, United States
E-mail: hunaid.nulwala@cm.netl.doe.gov, david.luebke@netl.doe.gov
Fax: +412-386-4604
Tel: +412-386-7343, +412-386-4118

b Department of Chemistry, University of Pittsburgh, Pittsburgh, PA, United States
E-mail: chau.tang@or.netl.doe.gov

c URS, P.O. Box 618, South Park, Pennsylvania, United States

d Department of Chemistry, Carnegie Mellon University, Pittsburgh, PA

Abstract

Understanding the structure-property relationship of ionic liquids is a key to the development of optimized materials for specific applications, such as CO2 capture, battery electrolytes, or lubricants. Using Cu(I)-catalyzed click chemistry as a synthetic platform, a library of triazolium-based ionic liquids has been accessed for the first time. These regioisomers of ionic liquids give insight into the structure property of these important materials. The effect of substituents and the effect of regioisomerization on thermal stability, CO2 solubility and inductive effects have been correlated.

Graphical abstract: Probing the structure-property relationship of regioisomeric ionic liquids with click chemistry

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Article information

DOI
https://doi.org/10.1039/C1GC16067B
Article type
Communication
Submitted
29 Aug 2011
Accepted
27 Sep 2011
First published
20 Oct 2011

Green Chem., 2011,13, 3345-3349

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Probing the structure-property relationship of regioisomeric ionic liquids with click chemistry

H. B. Nulwala, C. N. Tang, B. W. Kail, K. Damodaran, P. Kaur, S. Wickramanayake, W. Shi and D. R. Luebke, Green Chem., 2011, 13, 3345 DOI: 10.1039/C1GC16067B

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