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Issue 9, 2010
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Remarkable facilitation of hetero-cycloisomerizations with water and other polar protic solvents: metal-free synthesis of indolizines

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Abstract

Hetero-cycloisomerization reactions of propargylic alcohol derivatives leading to indolizines have been demonstrated to proceed in the presence of water alone. This stands as a significant advance over the previous methods using Pt, Cu or Ag salts paired with ligands in organic solvents such as benzene, acetonitrile or methylene chloride.

Graphical abstract: Remarkable facilitation of hetero-cycloisomerizations with water and other polar protic solvents: metal-free synthesis of indolizines

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The article was received on 09 Jun 2010, accepted on 14 Jul 2010 and first published on 10 Aug 2010


Article type: Communication
DOI: 10.1039/C0GC00198H
Citation: Green Chem., 2010,12, 1556-1559
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    Remarkable facilitation of hetero-cycloisomerizations with water and other polar protic solvents: metal-free synthesis of indolizines

    A. R. H. Narayan and R. Sarpong, Green Chem., 2010, 12, 1556
    DOI: 10.1039/C0GC00198H

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