Issue 9, 2010

Palladium-catalyzed cycloisomerization of (Z)-enynols into furans using green solvents: glycerolvs.water

Abstract

Heteroannulation reactions of (Z)-2-en-4-yn-1-ol derivatives into furans can be conveniently performed in water and glycerol using cis-[PdCl2(DAPTA)2] as catalyst. Higher activities were observed in an aqueous medium, but catalyst recycling was much more effective in glycerol.

Graphical abstract: Palladium-catalyzed cycloisomerization of (Z)-enynols into furans using green solvents: glycerol vs. water

Supplementary files

Article information

Article type
Communication
Submitted
02 Jun 2010
Accepted
12 Jul 2010
First published
03 Aug 2010

Green Chem., 2010,12, 1552-1555

Palladium-catalyzed cycloisomerization of (Z)-enynols into furans using green solvents: glycerol vs. water

J. Francos and V. Cadierno, Green Chem., 2010, 12, 1552 DOI: 10.1039/C0GC00169D

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