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Issue 3, 2009
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A reusable FeCl3·6H2O/cationic 2,2′-bipyridyl catalytic system for the coupling of aryl iodides with thiols in water under aerobic conditions

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Abstract

In this study, an FeCl3·6H2O/cationic 2,2′-bipyridyl system was employed as a catalyst in the coupling of aryl iodides with thiols to form an aryl–sulfur bond in refluxed water under aerobic conditions. The residual aqueous solution after extraction could be reused for several cycles without a significant decrease in activity.

Graphical abstract: A reusable FeCl3·6H2O/cationic 2,2′-bipyridyl catalytic system for the coupling of aryl iodides with thiols in water under aerobic conditions

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Publication details

The article was received on 20 Nov 2008, accepted on 14 Jan 2009 and first published on 22 Jan 2009


Article type: Communication
DOI: 10.1039/B820790A
Citation: Green Chem., 2009,11, 326-329
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    A reusable FeCl3·6H2O/cationic 2,2′-bipyridyl catalytic system for the coupling of aryl iodides with thiols in water under aerobic conditions

    W. Wu, J. Wang and F. Tsai, Green Chem., 2009, 11, 326
    DOI: 10.1039/B820790A

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