Issue 6, 2009
From the journal:

Green Chemistry

Highly-selective and high-speed Claisen rearrangement induced with subcritical water microreaction in the absence of catalyst†‡

Masahiro Sato,*a   Nobuhiro Otabe,b   Tomoya Tuji,b   Keiichiro Matsushima,c   Hajime Kawanami,*a   Maya Chatterjee,a   Toshiro Yokoyama,a   Yutaka Ikushimaa  and  Toshishige Maro Suzukia  

* Corresponding authors

a National Institute of Advanced Industrial Science and Technology (AIST), Research Center for Compact Chemical Process, 4-2-1 Nigatake, Miyagino-ku, Sendai, Japan
E-mail: masahiro-satou@aist.go.jp, h-kawanami@aist.go.jp
Fax: +81-22-237-5224
Tel: +81-22-237-2026

b Nihon University, Department of Applied Molecular Chemistry, College of Industrial Technology, 1-2-1 Izumicho, Narashino, Japan

c Hokkaido Industrial Research Institute, Department of Environmental Process Engineering, N19-W11, Kita-ku, Sapporo, Japan

Abstract

Highly-selective, high-speed aromatic and aliphatic Claisen rearrangement was shown to give the corresponding product in an excellent yield induced by subcritical water microreaction in the absence of catalyst.

Graphical abstract: Highly-selective and high-speed Claisen rearrangement induced with subcritical water microreaction in the absence of catalyst

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Article information

DOI
https://doi.org/10.1039/B819106A
Article type
Communication
Submitted
28 Oct 2008
Accepted
06 Mar 2009
First published
17 Mar 2009

Green Chem., 2009,11, 763-766

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Highly-selective and high-speed Claisen rearrangement induced with subcritical water microreaction in the absence of catalyst

M. Sato, N. Otabe, T. Tuji, K. Matsushima, H. Kawanami, M. Chatterjee, T. Yokoyama, Y. Ikushima and T. M. Suzuki, Green Chem., 2009, 11, 763 DOI: 10.1039/B819106A

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