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Issue 7, 2008
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Mild catalytic oxidation of secondary and tertiary amines to nitrones and N-oxides with H2O2 mediated by Pt(II) catalysts

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Abstract

Bridging hydroxo complexes of Pt(II) can be used as catalysts for the oxidation of tertiary and secondary amines under mild conditions using the environmentally benign hydrogen peroxide as the oxidant. The reaction proceeds with medium to excellent yields particularly in the case of the more electron rich tertiary amines.

Graphical abstract: Mild catalytic oxidation of secondary and tertiary amines to nitrones and N-oxides with H2O2 mediated by Pt(ii) catalysts

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Publication details

The article was received on 01 Apr 2008, accepted on 08 May 2008 and first published on 13 Jun 2008


Article type: Paper
DOI: 10.1039/B805404E
Citation: Green Chem., 2008,10, 793-798
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    Mild catalytic oxidation of secondary and tertiary amines to nitrones and N-oxides with H2O2 mediated by Pt(II) catalysts

    M. Colladon, A. Scarso and G. Strukul, Green Chem., 2008, 10, 793
    DOI: 10.1039/B805404E

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