Issue 5, 2008

Isolute®Si-carbonate catalyzes the nitronate addition to both aldehydes and electron-poor alkenes under solvent-free conditions

Abstract

It has been found that commercial ISOLUTE®Si-carbonate catalyzes both nitroaldol and Michael reactions, from nitroalkanes and under solvent-free conditions, allowing satisfactory to good yields of nitroalkanols and γ-nitro-functionalized carbonyl and cyano derivatives. In addition, a one-pot Henry–Michael reaction can be performed.

Graphical abstract: Isolute®Si-carbonate catalyzes the nitronate addition to both aldehydes and electron-poor alkenes under solvent-free conditions

Supplementary files

Article information

Article type
Paper
Submitted
18 Dec 2007
Accepted
11 Feb 2008
First published
05 Mar 2008

Green Chem., 2008,10, 541-544

Isolute®Si-carbonate catalyzes the nitronate addition to both aldehydes and electron-poor alkenes under solvent-free conditions

R. Ballini, G. Bosica, A. Palmieri, F. Pizzo and L. Vaccaro, Green Chem., 2008, 10, 541 DOI: 10.1039/B719477C

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