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Issue 5, 2008
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Isolute®Si-carbonate catalyzes the nitronate addition to both aldehydes and electron-poor alkenes under solvent-free conditions

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Abstract

It has been found that commercial ISOLUTE®Si-carbonate catalyzes both nitroaldol and Michael reactions, from nitroalkanes and under solvent-free conditions, allowing satisfactory to good yields of nitroalkanols and γ-nitro-functionalized carbonyl and cyano derivatives. In addition, a one-pot Henry–Michael reaction can be performed.

Graphical abstract: Isolute®Si-carbonate catalyzes the nitronate addition to both aldehydes and electron-poor alkenes under solvent-free conditions

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Publication details

The article was received on 18 Dec 2007, accepted on 11 Feb 2008 and first published on 05 Mar 2008


Article type: Paper
DOI: 10.1039/B719477C
Citation: Green Chem., 2008,10, 541-544
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    Isolute®Si-carbonate catalyzes the nitronate addition to both aldehydes and electron-poor alkenes under solvent-free conditions

    R. Ballini, G. Bosica, A. Palmieri, F. Pizzo and L. Vaccaro, Green Chem., 2008, 10, 541
    DOI: 10.1039/B719477C

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