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Issue 3, 2006
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Decomposition of ionic liquids in electrochemical processing

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Abstract

The stability of ionic liquids with respect to high voltage differences is important for their use in electrochemical applications. Ionic liquids decompose when voltage differences larger than their electrochemical window (4–6 V) are applied. However, little is known about the decomposition mechanism and products. In this work the electrochemical breakdown of the ionic liquids 1,1-butylmethylpyrrolidinium bis(trifluoromethylsulfonyl)imide and 1-butyl-3-methylimidazolium tetrafluoroborate on the cathode is predicted using quantum chemical calculations and validated by experiments. The quantum chemical calculations showed to be an excellent method to predict the electrochemical decomposition reactions and products.

Graphical abstract: Decomposition of ionic liquids in electrochemical processing

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Publication details

The article was received on 09 Sep 2005, accepted on 31 Oct 2005, published on 17 Nov 2005 and first published online on 17 Nov 2005


Article type: Paper
DOI: 10.1039/B512724F
Citation: Green Chem., 2006,8, 241-245
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    Decomposition of ionic liquids in electrochemical processing

    M. C. Kroon, W. Buijs, C. J. Peters and G. Witkamp, Green Chem., 2006, 8, 241
    DOI: 10.1039/B512724F

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