A (2 + 1) REMPI–PES study of HCl has been carried out in the two-photon energy region between 77 000 and 85 500 cm–1. The observed 1Δ(2), 3Δ(2), 3Π(1) and 3Σ–(0+) states are characterized as Rydberg states. The one-photon ionization of the B 1Σ+ state has been shown to be dominated by indirect processes involving competition between electronic autoionization and dissociation via superexcited states.
E. de Beer, B. G. Koenders, M. P. Koopmans and C. A. de Lange, J. Chem. Soc., Faraday Trans., 1990, 86, 2035 DOI: 10.1039/FT9908602035
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