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Issue 0, 1978
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Thermodynamic properties of a fluid of polarizable hard spheres with multipolar interactions

Abstract

Molar volume, compressibility, entropy and Gibbs' free energy are calculated for a system of polarizable hard spheres with permanent ideal dipoles and/or quadrupoles as functions of pressure, temperature, polarizability, dipole moments and quadrupole moments by use of thermodynamic perturbation theory. These properties, and the vapour/liquid coexistence curve as predicted by the same theory, are discussed in terms of the relative importance of the dipole and quadrupole moments.

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Article type: Paper
DOI: 10.1039/F29787401778
Citation: J. Chem. Soc., Faraday Trans. 2, 1978,74, 1778-1788
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    Thermodynamic properties of a fluid of polarizable hard spheres with multipolar interactions

    E. Morild and B. Larsen, J. Chem. Soc., Faraday Trans. 2, 1978, 74, 1778
    DOI: 10.1039/F29787401778

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