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Issue 11, 2014
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Hybrid capacitive deionization to enhance the desalination performance of capacitive techniques

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Abstract

Based on a porous carbon electrode, capacitive deionization (CDI) is a promising desalination technology in which ions are harvested and stored in an electrical double layer. However, the ion removal capacity of CDI systems is not sufficient for desalting high-concentration saline water. Here, we report a novel desalination technique referred to as “hybrid capacitive deionization (HCDI)”, which combines CDI with a battery system. HCDI consists of a sodium manganese oxide (Na4Mn9O18) electrode, an anion exchange membrane, and a porous carbon electrode. In this system, sodium ions are captured by the chemical reaction in the Na4Mn9O18 electrode, whereas chloride ions are adsorbed on the surface of the activated carbon electrode during the desalination process. HCDI exhibited more than double the ion removal sorption capacity (31.2 mg g−1) than a typical CDI system (13.5 mg g−1). Moreover, it was found that the system has a rapid ion removal rate and excellent stability in an aqueous sodium chloride solution. These results thus suggest that the HCDI system could be a feasible method for desalting a highly concentrated sodium chloride solution in capacitive techniques.

Graphical abstract: Hybrid capacitive deionization to enhance the desalination performance of capacitive techniques

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Publication details

The article was received on 28 Jul 2014, accepted on 20 Aug 2014 and first published on 20 Aug 2014


Article type: Paper
DOI: 10.1039/C4EE02378A
Author version available: Download Author version (PDF)
Citation: Energy Environ. Sci., 2014,7, 3683-3689
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    Hybrid capacitive deionization to enhance the desalination performance of capacitive techniques

    J. Lee, S. Kim, C. Kim and J. Yoon, Energy Environ. Sci., 2014, 7, 3683
    DOI: 10.1039/C4EE02378A

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