Jump to main content
Jump to site search

Issue 6, 2011
Previous Article Next Article

Implications of remote water molecules on the electron transfer coupled processes at a nonporphyrinic Mn(III)-hydroxido complex

Author affiliations

Abstract

Electrochemical studies of a new Mn(III)(OH) complex clearly evidence that the presence of outer spheres water molecules is essential for the reversibility of MnIII/II and MnIV/IIIredox processes. In the MnIII/II case we found an isotope effect for D2O and 18OH2 allowing us to propose a mechanism for H2O/HO ligand exchange coupled electron transfer activation of Mn–OH2

Graphical abstract: Implications of remote water molecules on the electron transfer coupled processes at a nonporphyrinic Mn(iii)-hydroxido complex

Back to tab navigation

Supplementary files

Publication details

The article was received on 21 Jan 2011, accepted on 31 Mar 2011 and first published on 19 Apr 2011


Article type: Communication
DOI: 10.1039/C1EE01078F
Citation: Energy Environ. Sci., 2011,4, 2041-2044
  •   Request permissions

    Implications of remote water molecules on the electron transfer coupled processes at a nonporphyrinic Mn(III)-hydroxido complex

    S. El Ghachtouli, B. Lassalle-Kaiser, P. Dorlet, R. Guillot, E. Anxolabéhère-Mallart, C. Costentin and A. Aukauloo, Energy Environ. Sci., 2011, 4, 2041
    DOI: 10.1039/C1EE01078F

Search articles by author

Spotlight

Advertisements