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Issue 7, 2011
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Spectroscopically characterized intermediates of catalytic H2 formation by [FeFe] hydrogenase models

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Abstract

This review compiles species that are known or potential intermediates in the catalytic formation of H2 by diiron dithiolate complexes inspired by the active site of the [FeFe] hydrogenases. The data collection emphasizes spectroscopic characteristics (NMR, IR, UV-Vis, EPR) of protonated and reduced derivatives of the iron complexes that could provide reference data to the identification of intermediates in mechanistic studies.

Graphical abstract: Spectroscopically characterized intermediates of catalytic H2 formation by [FeFe] hydrogenase models

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Publication details

The article was received on 24 Nov 2010, accepted on 10 Jan 2011 and first published on 28 Feb 2011


Article type: Review Article
DOI: 10.1039/C0EE00708K
Citation: Energy Environ. Sci., 2011,4, 2340-2352
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    Spectroscopically characterized intermediates of catalytic H2 formation by [FeFe] hydrogenase models

    S. Tschierlei, S. Ott and R. Lomoth, Energy Environ. Sci., 2011, 4, 2340
    DOI: 10.1039/C0EE00708K

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