Issue 35, 2018

Dinuclear tethered pyridine, diimine complexes

Abstract

The regioselective borylation of pyridine precursors, followed by Suzuki coupling with dihalogenated linker molecules, provides access to tethered ligands. Complexation with MX2 salts results in the formation of dinuclear metal compounds. Syntheses and crystal structures are reported along with a discussion on the rigidity/flexibility of these new ligand systems.

Graphical abstract: Dinuclear tethered pyridine, diimine complexes

Supplementary files

Article information

Article type
Paper
Submitted
07 Jun 2018
Accepted
22 Jul 2018
First published
23 Jul 2018
This article is Open Access
Creative Commons BY-NC license

Dalton Trans., 2018,47, 12105-12117

Dinuclear tethered pyridine, diimine complexes

W. Dammann, T. Buban, C. Schiller and P. Burger, Dalton Trans., 2018, 47, 12105 DOI: 10.1039/C8DT02347F

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