Issue 10, 2018
From the journal:

Dalton Transactions

Synthesis and characterization of an iron complex bearing a hemilabile NNN-pincer for catalytic hydrosilylation of organic carbonyl compounds†

Hsiu-Jung Lin,a   Sean Lutz,b   Catherine O'Kane,a   Matthias Zeller,c   Chun-Hsing Chen,b   Talal Al Assila  and  Wei-Tsung Lee ORCID logo *a  

* Corresponding authors

a Department of Chemistry and Biochemistry, Loyola University Chicago, Chicago, IL 60660, USA
E-mail: wlee5@luc.edu
Fax: +1-773-508-3086
Tel: +1-773-508-3205

b Department of Chemistry, Indiana University, Bloomington, IN 47405, USA

c Department of Chemistry, Purdue University, West Lafayette, IN 47907, USA

Abstract

A low-coordinate iron(II) complex (CztBu(PztBu)2)Fe[N(SiMe3)2], 1 bearing an NNN-pincer ligand was prepared and fully characterized. Intramolecular C–H activation on the 5-position of a pyrazole at elevated temperatures was observed. Complex 1 was found to be an efficient and chemoselective pre-catalyst for the hydrosilylation of organo carbonyl substrates.

Graphical abstract: Synthesis and characterization of an iron complex bearing a hemilabile NNN-pincer for catalytic hydrosilylation of organic carbonyl compounds

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Article information

DOI
https://doi.org/10.1039/C7DT04928E
Article type
Communication
Submitted
03 Jan 2018
Accepted
26 Jan 2018
First published
26 Jan 2018

Dalton Trans., 2018,47, 3243-3247

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Synthesis and characterization of an iron complex bearing a hemilabile NNN-pincer for catalytic hydrosilylation of organic carbonyl compounds

H. Lin, S. Lutz, C. O'Kane, M. Zeller, C. Chen, T. Al Assil and W. Lee, Dalton Trans., 2018, 47, 3243 DOI: 10.1039/C7DT04928E

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