Issue 6, 2018
From the journal:

Dalton Transactions

A novel trigonal propeller-shaped hybrid tri-neodymium-polyoxometalate exhibiting single-molecule magnet behavior†

Hai-Long Zhang, ORCID logo a   Xiao-Yuan Wu, ORCID logo a   Jian-Zhen Liao, ORCID logo a   Xiao-Fei Kuang,b   Wenbin Yang ORCID logo *a  and  Can-Zhong Lu ORCID logo *ab  

* Corresponding authors

a Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, P. R. China
E-mail: czlu@fjirsm.ac.cn
Fax: (+86)591-83714946
Tel: (+86)591-83705794

b Xiamen Institute of Rare-earth Materials, Haixi Institutes, Chinese Academy of Sciences, Fujian 361005, P. R. China

Abstract

A trigonal propeller-shaped hybrid polyoxometalate (POM) (NH2Me2)3{[Nd(Mo4O13)(DMF)4]3(BTC)2}·8DMF (1; BTC = 1,3,5-benzenetricarboxylate) has been synthesized and structurally characterized. The planar {Mo4} segment is tailored from the precursor Lindqvist polyoxoanion [Mo6O19]2− firstly, and plays a key role in the reassembly of 1. Furthermore, the magnetic studies reveal that 1 shows single-molecule magnet (SMM) behavior.

Graphical abstract: A novel trigonal propeller-shaped hybrid tri-neodymium-polyoxometalate exhibiting single-molecule magnet behavior

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Article information

DOI
https://doi.org/10.1039/C7DT04908K
Article type
Communication
Submitted
28 Dec 2017
Accepted
08 Jan 2018
First published
08 Jan 2018

Dalton Trans., 2018,47, 1796-1800

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A novel trigonal propeller-shaped hybrid tri-neodymium-polyoxometalate exhibiting single-molecule magnet behavior

H. Zhang, X. Wu, J. Liao, X. Kuang, W. Yang and C. Lu, Dalton Trans., 2018, 47, 1796 DOI: 10.1039/C7DT04908K

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