Issue 44, 2017
From the journal:

Dalton Transactions

A trans-bidentate bis-pyridinyl ligand with a transition metal hinge†

Noah C. Vieira,a   Jared A. Pienkos,*a   Colin D. McMillen, ORCID logo b   Alexis R. Myers,a   Alyssa P. Claya  and  Paul S. Wagenknecht ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Furman University, Greenville, SC, USA

b Department of Chemistry, Clemson University, Clemson, SC, USA

Abstract

A titanocene based metalloligand, Cp*2Ti(C22-py)2, was synthesized and coordinated to either Cu(I) or Pd(II). The metalloligand binds Cu(I) between its alkynes and Pd(II) between its pyridinyl rings, acting as a trans-bidentate ligand. In order to bind Pd(II), significant structural rearrangements were necessary, which required the flexibility of the C–Ti–C hinge on the titanocene metalloligand.

Graphical abstract: A trans-bidentate bis-pyridinyl ligand with a transition metal hinge

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Article information

DOI
https://doi.org/10.1039/C7DT03252H
Article type
Communication
Submitted
01 Sep 2017
Accepted
18 Oct 2017
First published
19 Oct 2017

Dalton Trans., 2017,46, 15195-15199

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A trans-bidentate bis-pyridinyl ligand with a transition metal hinge

N. C. Vieira, J. A. Pienkos, C. D. McMillen, A. R. Myers, A. P. Clay and P. S. Wagenknecht, Dalton Trans., 2017, 46, 15195 DOI: 10.1039/C7DT03252H

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