Issue 37, 2017

Observation of magnetic interactions between localized 4f- and itinerant π-electrons in a single crystal of cationic bisphthalocyanine complexes containing diluted spin centres

Abstract

Magnetic f–π interactions between localized 4f-electrons and itinerant π-electrons have been observed in a single crystal of bisphthalocyaninato yttrium(III)/terbium(III) tetrafluoroborate ([Pc2Y0.95Tb0.05][BF4]) by measuring electrical conductivity of the crystal in the presence of an external magnetic field.

Graphical abstract: Observation of magnetic interactions between localized 4f- and itinerant π-electrons in a single crystal of cationic bisphthalocyanine complexes containing diluted spin centres

Supplementary files

Article information

Article type
Communication
Submitted
21 Jul 2017
Accepted
21 Aug 2017
First published
21 Aug 2017

Dalton Trans., 2017,46, 12421-12424

Observation of magnetic interactions between localized 4f- and itinerant π-electrons in a single crystal of cationic bisphthalocyanine complexes containing diluted spin centres

T. Fukuda, S. Onodera, H. Watanabe, K. Shirasaki, A. Fuyuhiro, T. Yamamura and N. Ishikawa, Dalton Trans., 2017, 46, 12421 DOI: 10.1039/C7DT02656K

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