A mild post-functionalization method for the vanadium substituted P2W15V3 Wells–Dawson polyoxometalate based on a copper catalyzed azide–alkyne cycloaddition

S. Vanhaecht; T. Quanten; T. N. Parac-Vogt

doi:10.1039/C7DT02450A

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A mild post-functionalization method for the vanadium substituted P₂W₁₅V₃ Wells–Dawson polyoxometalate based on a copper catalyzed azide–alkyne cycloaddition†

S. Vanhaecht,^a T. Quanten^a and T. N. Parac-Vogt

*^a

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* Corresponding authors

^a Department of Chemistry, KU Leuven, Celestijnenlaan 200F, 3001 Leuven, Belgium
E-mail: tatjana.vogt@kuleuven.be
Tel: +32 (0)16 327612

Abstract

A mild post-functionalization method, based on a copper(I) catalyzed azide–alkyne cycloaddition, was developed for the fragile [P₂W₁₅V₃]⁹⁻ (PWV). PWV was functionalized with an azide and used as a platform to attach various alkyne functionalized compounds.

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Article information

DOI: https://doi.org/10.1039/C7DT02450A
Article type: Communication
Submitted: 06 Jul 2017
Accepted: 12 Jul 2017
First published: 17 Jul 2017

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Dalton Trans., 2017,46, 10215-10219

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A mild post-functionalization method for the vanadium substituted P₂W₁₅V₃ Wells–Dawson polyoxometalate based on a copper catalyzed azide–alkyne cycloaddition

S. Vanhaecht, T. Quanten and T. N. Parac-Vogt, Dalton Trans., 2017, 46, 10215 DOI: 10.1039/C7DT02450A

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Dalton Transactions