Creation of bismuth–tungsten oxide nanoclusters using lacunary polyoxometalates

Takumi Hanaya; Kosuke Suzuki; Rinta Sato; Kazuya Yamaguchi; Noritaka Mizuno

doi:10.1039/C7DT01587A

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Creation of bismuth–tungsten oxide nanoclusters using lacunary polyoxometalates†

Takumi Hanaya,^a Kosuke Suzuki,

*^a Rinta Sato,^a Kazuya Yamaguchi

^a and Noritaka Mizuno*^a

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* Corresponding authors

^a Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan
E-mail: ksuzuki@appchem.t.u-tokyo.ac.jp, tmizuno@mail.ecc.u-tokyo.ac.jp
Fax: +81-3-5841-7220

Abstract

Three types of heterometallic bismuth–tungsten oxide nanoclusters were successfully synthesized by the reactions of lacunary silicotungstates (trivacant [A-α-SiW₉O₃₄]¹⁰⁻ and divacant [γ-SiW₁₀O₃₆]⁸⁻) and Bi³⁺ in organic solvents. Lone pairs on Bi³⁺ acted as structure-directing groups in these nanoclusters.

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DOI: https://doi.org/10.1039/C7DT01587A
Article type: Communication
Submitted: 01 May 2017
Accepted: 11 May 2017
First published: 11 May 2017

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Dalton Trans., 2017,46, 7384-7387

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Creation of bismuth–tungsten oxide nanoclusters using lacunary polyoxometalates

T. Hanaya, K. Suzuki, R. Sato, K. Yamaguchi and N. Mizuno, Dalton Trans., 2017, 46, 7384 DOI: 10.1039/C7DT01587A

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Dalton Transactions

Creation of bismuth–tungsten oxide nanoclusters using lacunary polyoxometalates†

Abstract

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Creation of bismuth–tungsten oxide nanoclusters using lacunary polyoxometalates

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