Issue 30, 2017

Pyrite form of group-14 element pernitrides synthesized at high pressure and high temperature

Abstract

The chemical reaction of group-14 elements with molecular nitrogen at pressures above 60 GPa successfully leads to the formation of pyrite-type pernitrides. These new crystalline group-14 elemental pernitrides were found to show a bulk modulus higher than the other known group-14 elemental nitrides. Our results offer significant new progress in the solid-state chemistry of nitrides.

Graphical abstract: Pyrite form of group-14 element pernitrides synthesized at high pressure and high temperature

Supplementary files

Article information

Article type
Communication
Submitted
30 Apr 2017
Accepted
29 Jun 2017
First published
29 Jun 2017

Dalton Trans., 2017,46, 9750-9754

Pyrite form of group-14 element pernitrides synthesized at high pressure and high temperature

K. Niwa, H. Ogasawara and M. Hasegawa, Dalton Trans., 2017, 46, 9750 DOI: 10.1039/C7DT01583F

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