Chiral two bladed ML2 metallamacrocycles: design, structures and solution behavior

Hannah Soudry; Christophe Desmarets; Geoffrey Gontard; Tiffany Edgington; Andrew L. Cooksy; Hani Amouri

doi:10.1039/C7DT01151B

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Chiral two bladed ML₂ metallamacrocycles: design, structures and solution behavior†

Hannah Soudry,^a Christophe Desmarets,*^a Geoffrey Gontard,^a Tiffany Edgington,^b Andrew L. Cooksy^b and Hani Amouri

*^a

Author affiliations

* Corresponding authors

^a Sorbonne Universités, UPMC Univ Paris 06, Université Pierre et Marie Curie, Institut Parisien de Chimie Moléculaire (IPCM) UMR 8232, 4 place Jussieu, 75252 Paris cedex 05, France
E-mail: christophe.desmarets@upmc.fr, hani.amouri@upmc.fr

^b Department of Chemistry, San Diego State University, San Diego, CA 92182-1030, USA

Abstract

Chiral two bladed complexes of [Co(L)₂][BF₄]₂ (1) and [Zn(L)₂][BF₄]₂ (2) containing an atropoisomeric semi-rigid bidentate ligand L were synthesized and characterized. They are obtained as homochiral species but in a racemic mixture via a ligand self-sorting mechanism. These enantiomers can be differentiated in solution using optically active anions.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C7DT01151B
Article type: Paper
Submitted: 30 Mar 2017
Accepted: 04 Jul 2017
First published: 21 Jul 2017

Download Citation

Dalton Trans., 2017,46, 10240-10245

Permissions

Request permissions

Chiral two bladed ML₂ metallamacrocycles: design, structures and solution behavior

H. Soudry, C. Desmarets, G. Gontard, T. Edgington, A. L. Cooksy and H. Amouri, Dalton Trans., 2017, 46, 10240 DOI: 10.1039/C7DT01151B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Dalton Transactions