Issue 24, 2017

A novel synthesis of an Fe3+/Fe2+ layered double hydroxide (‘green rust’) via controlled electron transfer with a conducting polymer

Abstract

This report examines the influence of a conducting polymer on the crystal growth of labile green rust (GR) through hybridization with polypyrrole. All hybrids used in this study were prepared via one-pot co-precipitation at neutral pH, with specific stoichiometric ratios among all chemical species. The role of the conducting polymer and the effective stoichiometric ratio were demonstrated to facilitate the crystal growth of GR.

Graphical abstract: A novel synthesis of an Fe3+/Fe2+ layered double hydroxide (‘green rust’) via controlled electron transfer with a conducting polymer

Supplementary files

Article information

Article type
Communication
Submitted
28 Feb 2017
Accepted
30 Apr 2017
First published
17 May 2017

Dalton Trans., 2017,46, 7656-7659

A novel synthesis of an Fe3+/Fe2+ layered double hydroxide (‘green rust’) via controlled electron transfer with a conducting polymer

M. Kim, T. Kim, Y. S. Seo, J. Oh and J. K. Park, Dalton Trans., 2017, 46, 7656 DOI: 10.1039/C7DT00731K

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