Benzoquinone-bridged Co2 complexes with different magnetic anisotropy induced by solvent molecules

Wenhai Cao; Xiaoquan Zhu; Pengfei Liu; Shaodong Su; Shengmin Hu; Yuehong Wen; Xintao Wu; Tianlu Sheng

doi:10.1039/C6DT04420D

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Benzoquinone-bridged Co₂ complexes with different magnetic anisotropy induced by solvent molecules†

Wenhai Cao,^ab Xiaoquan Zhu,^ab Pengfei Liu,

^ab Shaodong Su,^ab Shengmin Hu,^a Yuehong Wen,^a Xintao Wu^a and Tianlu Sheng

*^a

Author affiliations

* Corresponding authors

^a State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, China
E-mail: tsheng@fjirsm.ac.cn

^b School of Chemistry and Chemical Engineering, University of Chinese Academy of Sciences, Beijing, China

Abstract

The first example of discrete small molecular compounds with different magnetic anisotropy induced by solvent molecules, benzoquinone-bridged Co₂ complexes, [(TPyA)₂Co₂(L)]·solvent (L = 2,5-dibromo-3,6-dihydroxy-1,4-benzoquinone, solvent = CH₃CN and H₂O), has been prepared and fully characterized.

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Article information

DOI: https://doi.org/10.1039/C6DT04420D
Article type: Communication
Submitted: 22 Nov 2016
Accepted: 08 Feb 2017
First published: 09 Feb 2017

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Dalton Trans., 2017,46, 3435-3437

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Benzoquinone-bridged Co₂ complexes with different magnetic anisotropy induced by solvent molecules

W. Cao, X. Zhu, P. Liu, S. Su, S. Hu, Y. Wen, X. Wu and T. Sheng, Dalton Trans., 2017, 46, 3435 DOI: 10.1039/C6DT04420D

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Dalton Transactions