Issue 3, 2017
From the journal:

Dalton Transactions

Unexpected alkane elimination from cationic group 13 dialkyls in a reaction with a macrocyclic polyamine†

Debabrata Mukherjee,a   Thomas P. Spaniola  and  Jun Okuda ORCID logo *a  

* Corresponding authors

a Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, Aachen, Germany
E-mail: jun.okuda@ac.rwth-aachen.de

Abstract

A macrocyclic polyamine 1,4,7-trimethyl-1,4,7,10-tetraazacyclododecane, (Me3TACD)H formed thermally stable adducts with MMe3 (M = Al, In). The reactions with cationic dialkyls [MR2]+ directly provided cationic monoalkyls [(Me3TACD)MR]+ under RH elimination. Reactions between [Li(Me3TACD)]2 and Me2MCl gave chloro-bridged heterobimetallic adducts.

Graphical abstract: Unexpected alkane elimination from cationic group 13 dialkyls in a reaction with a macrocyclic polyamine

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Article information

DOI
https://doi.org/10.1039/C6DT04379H
Article type
Communication
Submitted
17 Nov 2016
Accepted
02 Dec 2016
First published
02 Dec 2016

Dalton Trans., 2017,46, 651-655

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Unexpected alkane elimination from cationic group 13 dialkyls in a reaction with a macrocyclic polyamine

D. Mukherjee, T. P. Spaniol and J. Okuda, Dalton Trans., 2017, 46, 651 DOI: 10.1039/C6DT04379H

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