Issue 41, 2016
From the journal:

Dalton Transactions

An unusual assembled Pb(ii) meso-helicate that shows the inert pair effect†

María J. Romero,a   Rocío Carballido,a   Laura Rodríguez-Silva,b   Marcelino Maneiro,b   Guillermo Zaragoza,c   Ana M. González-Noya*a  and  Rosa Pedrido*a  

* Corresponding authors

a Departamento de Química Inorgánica, Facultade de Química, Campus Vida, Universidade de Santiago de Compostela, Santiago de Compostela, Galicia, Spain
E-mail: rosa.pedrido@usc.es

b Departamento de Química Inorgánica, Facultade de Ciencias, Universidade de Santiago de Compostela, Lugo, Galicia, Spain

c Unidade de Difracción de Raios X, Edificio CACTUS, Universidade de Santiago de Compostela, Campus Sur, Santiago de Compostela, Galicia, Spain

Abstract

A dinuclear Pb(II) mesocate has been prepared with an unprecedented four-coordinated kernel in which the Pb(II) lone pair is stereochemically active. This is the first time that this effect has been observed in a supramolecular Pb(II) helicate or meso-helicate.

Graphical abstract: An unusual assembled Pb(ii) meso-helicate that shows the inert pair effect

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Article information

DOI
https://doi.org/10.1039/C6DT03106D
Article type
Communication
Submitted
04 Aug 2016
Accepted
16 Sep 2016
First published
16 Sep 2016

Dalton Trans., 2016,45, 16162-16165

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An unusual assembled Pb(II) meso-helicate that shows the inert pair effect

M. J. Romero, R. Carballido, L. Rodríguez-Silva, M. Maneiro, G. Zaragoza, A. M. González-Noya and R. Pedrido, Dalton Trans., 2016, 45, 16162 DOI: 10.1039/C6DT03106D

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