Rhodium(I), rhodium(III) and iridium(III) carbaporphyrins

Venkata A. K. Adiraju; Gregory M. Ferrence; Timothy D. Lash

doi:10.1039/C6DT03093A

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Rhodium(i), rhodium(iii) and iridium(iii) carbaporphyrins†

Venkata A. K. Adiraju,

^a Gregory M. Ferrence

^a and Timothy D. Lash*^a

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* Corresponding authors

^a Department of Chemistry, Illinois State University, Normal, Illinois 61790-4160, USA
E-mail: tdlash@ilstu.edu

Abstract

Treatment of a benzocarbaporphyrin with [Rh(CO)₂Cl]₂ in refluxing dichloromethane gave a rhodium(I) dicarbonyl complex, and further reaction in refluxing pyridine afforded an organometallic rhodium(III) derivative. The carbaporphyrin also reacted with [Ir(COD)Cl]₂ and pyridine in refluxing p-xylene to generate a related iridium(III) compound. These novel metalated porphyrinoids retained strongly diatropic characteristics and were fully characterized by XRD.

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DOI: https://doi.org/10.1039/C6DT03093A
Article type: Communication
Submitted: 03 Aug 2016
Accepted: 10 Aug 2016
First published: 10 Aug 2016

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Dalton Trans., 2016,45, 13691-13694

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Rhodium(I), rhodium(III) and iridium(III) carbaporphyrins

V. A. K. Adiraju, G. M. Ferrence and T. D. Lash, Dalton Trans., 2016, 45, 13691 DOI: 10.1039/C6DT03093A

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Dalton Transactions

Rhodium(i), rhodium(iii) and iridium(iii) carbaporphyrins†

Abstract

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Rhodium(I), rhodium(III) and iridium(III) carbaporphyrins

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