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Issue 30, 2016
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Fischer–Tropsch synthesis over MOF-supported cobalt catalysts (Co@MIL-53(Al))

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Abstract

Novel nanohybrid materials were prepared by immobilizing Co nanoparticles on a microporous framework MIL-53(Al) as a porous host matrix. The synthesized cobalt-containing materials were characterized by XRD, STEM, and oxygen titration. The catalytic performance of Co@MIL-53(Al) nanohybrids was examined in Fischer–Tropsch synthesis (FTS) for the first time. A higher selectivity to C5+ hydrocarbons and lower selectivity to methane for Co@MIL-53(Al) as compared to conventional Co/Al2O3 were observed.

Graphical abstract: Fischer–Tropsch synthesis over MOF-supported cobalt catalysts (Co@MIL-53(Al))

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Publication details

The article was received on 11 Apr 2016, accepted on 29 Jun 2016 and first published on 29 Jun 2016


Article type: Paper
DOI: 10.1039/C6DT01394E
Citation: Dalton Trans., 2016,45, 12006-12014
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    Fischer–Tropsch synthesis over MOF-supported cobalt catalysts (Co@MIL-53(Al))

    V. I. Isaeva, O. L. Eliseev, R. V. Kazantsev, V. V. Chernyshev, P. E. Davydov, B. R. Saifutdinov, A. L. Lapidus and L. M. Kustov, Dalton Trans., 2016, 45, 12006
    DOI: 10.1039/C6DT01394E

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