Issue 22, 2016
From the journal:

Dalton Transactions

Lead ion induced chemodosimeter approach of a tripodal hydroxyl-quinoline based phospho-ester through P–O bond cleavage†

Dibyendu Sain,‡a   Chanda Kumari,a   Ashish Kumar,a   Hari Pada Nayeka  and  Swapan Dey*a  

* Corresponding authors

a Department of Applied Chemistry, Indian School of Mines, Dhanbad, Jharkhand, India
E-mail: dey.s.ac@ismdhanbad.ac.in, hpnayek@yahoo.com
Fax: +91 326 2296563
Tel: +91 326 2235607

Abstract

Lead ion induced P–O bond breaking with instant colour change was observed in a tripodal hydroxyl-quinoline based phosphor-ester (HQP). A new penta-coordinated lead chelate complex [Pb4HQ6(ClO4)2] was found. The hydrolysis reaction followed by P–O bond cleavage with ‘Pb–O’ and ‘Pb–N’ bond formation proved the chemodosimeter approach.

Graphical abstract: Lead ion induced chemodosimeter approach of a tripodal hydroxyl-quinoline based phospho-ester through P–O bond cleavage

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C6DT00941G
Article type
Paper
Submitted
09 Mar 2016
Accepted
25 Apr 2016
First published
12 May 2016

Dalton Trans., 2016,45, 9187-9192

Permissions

Request permissions

Lead ion induced chemodosimeter approach of a tripodal hydroxyl-quinoline based phospho-ester through P–O bond cleavage

D. Sain, C. Kumari, A. Kumar, H. P. Nayek and S. Dey, Dalton Trans., 2016, 45, 9187 DOI: 10.1039/C6DT00941G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements