Issue 5, 2016

Synthesis and self-assembly of carbamoylmethylphosphonate acrylamide-based diblock copolymers: new valuable thermosensitive materials

Abstract

We report the synthesis by RAFT polymerization of well-defined diblock copolymers bearing carbamoylmethylphosphonate moieties which proved to sorb gadolinium. These poly(diethyl-6-(acrylamido)hexylcarbamoylmethylphosphonate-b-acrylic acid) (P(CPAAm6C-b-AA)) copolymers were able to self-assemble as a function of temperature, above their cloud point value.

Graphical abstract: Synthesis and self-assembly of carbamoylmethylphosphonate acrylamide-based diblock copolymers: new valuable thermosensitive materials

Supplementary files

Article information

Article type
Communication
Submitted
25 Aug 2015
Accepted
18 Sep 2015
First published
18 Sep 2015

Dalton Trans., 2016,45, 1881-1885

Author version available

Synthesis and self-assembly of carbamoylmethylphosphonate acrylamide-based diblock copolymers: new valuable thermosensitive materials

F. Azemar, D. Gomes-Rodrigues, J. Robin and S. Monge, Dalton Trans., 2016, 45, 1881 DOI: 10.1039/C5DT03289J

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