Issue 29, 2015

Chiral porous metal–organic frameworks containing μ-oxo-bis[Ti(salan)] units for asymmetric cyanation of aldehydes

Abstract

Two chiral porous Ti(salan)-based metal–organic frameworks are constructed and are shown to be efficient and recyclable heterogeneous catalysts for asymmetric cyanation reaction of aldehydes, displaying significantly higher enantioselectivity than their homogeneous counterpart.

Graphical abstract: Chiral porous metal–organic frameworks containing μ-oxo-bis[Ti(salan)] units for asymmetric cyanation of aldehydes

Supplementary files

Article information

Article type
Communication
Submitted
04 May 2015
Accepted
23 Jun 2015
First published
24 Jun 2015

Dalton Trans., 2015,44, 12999-13002

Chiral porous metal–organic frameworks containing μ-oxo-bis[Ti(salan)] units for asymmetric cyanation of aldehydes

X. Du, Z. Li, Y. Liu, S. Yang and Y. Cui, Dalton Trans., 2015, 44, 12999 DOI: 10.1039/C5DT01682G

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