Issue 18, 2015
From the journal:

Dalton Transactions

A new vanadium sulfate with ferrimagnetic and NLO properties constructed from novel discrete umbrella-like [VV(μ3-O)4VIV4O5(SO4)4(en)]5− anions†

Shuai Zhou,a   Hongxiang Wan,a   Gonghao Hu,a   Yu Zhang,a   Ying Liu,a   Hao Miao,a   Dunru Zhua  and  Yan Xu*ab  

* Corresponding authors

a College of Chemistry and Chemical Engineering, State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing University of Technology, Nanjing 210009, PR China
E-mail: yanxu@njtech.edu.cn

b Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, PR China

Abstract

A new vanadium sulfate, [H2N(CH3)2]19/3(en)[V5O5(μ3-O)4(SO4)4](SO4)2/3[HN(CH3)2]2/31, constructed from novel umbrella-like [VV(μ3-O)4VIV4O5(SO4)4(en)]5− anions was synthesized and structurally characterized using single-crystal X-ray analysis. The magnetic and optical studies of 1 indicate that the title compound exhibits significant ZFS (zero field splitting), interesting ferrimagnetic interactions and strong two photon absorption.

Graphical abstract: A new vanadium sulfate with ferrimagnetic and NLO properties constructed from novel discrete umbrella-like [VV(μ3-O)4VIV4O5(SO4)4(en)]5− anions

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Article information

DOI
https://doi.org/10.1039/C5DT01026H
Article type
Communication
Submitted
14 Mar 2015
Accepted
25 Mar 2015
First published
25 Mar 2015

Dalton Trans., 2015,44, 8605-8608

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A new vanadium sulfate with ferrimagnetic and NLO properties constructed from novel discrete umbrella-like [VV(μ3-O)4VIV4O5(SO4)4(en)]5− anions

S. Zhou, H. Wan, G. Hu, Y. Zhang, Y. Liu, H. Miao, D. Zhu and Y. Xu, Dalton Trans., 2015, 44, 8605 DOI: 10.1039/C5DT01026H

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