The stoichiometric reaction of para-methoxyanilines and B(C6F5)3 under H2 results in reduction of the N-bound phenyl ring(s), and subsequent transannular ring closure with elimination of methanol, affording the respective 7-azabicyclo[2.2.1]heptane derivatives.
L. E. Longobardi, T. Mahdi and D. W. Stephan, Dalton Trans., 2015, 44, 7114 DOI: 10.1039/C5DT00921A
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