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Issue 30, 2015
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A CO32−-containing, dimanganese-substituted silicotungstate trimer, K9[H14{SiW10MnIIMnIIIO38}3(CO3)]·39H2O

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Abstract

An unprecedented silicotungstate trimer K9[H14{SiW10MnIIMnIIIO38}3(CO3)]·39H2O (1) has been successfully synthesized, in which the CO32− resides inside the three Keggin {SiW10MnIIMnIIIO38} units and the three O atoms serve as μ2-O atoms to connect with three MnIII. Magnetic investigation indicates that 1 exhibits antiferromagnetic coupling.

Graphical abstract: A CO32−-containing, dimanganese-substituted silicotungstate trimer, K9[H14{SiW10MnIIMnIIIO38}3(CO3)]·39H2O

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Publication details

The article was received on 20 Jan 2015, accepted on 25 Jun 2015 and first published on 26 Jun 2015


Article type: Communication
DOI: 10.1039/C5DT00262A
Citation: Dalton Trans., 2015,44, 13469-13472
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    A CO32−-containing, dimanganese-substituted silicotungstate trimer, K9[H14{SiW10MnIIMnIIIO38}3(CO3)]·39H2O

    L. Yang, Q. Liu, P. Ma, J. Niu and J. Wang, Dalton Trans., 2015, 44, 13469
    DOI: 10.1039/C5DT00262A

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