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New 10-vertex rhodathiaboranes are reported to exhibit reversible reaction chemistry leading to the formation of stoichiometric cycles driven by oxidation/reduction chemistry of the polyhedral boron-based clusters with ethelyne and dihydrogen.
![Graphical abstract: Rhodathiaborane reaction cycles driven by C2H4 and H2: synthesis and characterization of [(H)2(PPh3)RhSB8H7(PPh3)] and [(η2-C2H4)(PPh3)RhSB8H7(PPh3)]](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=C4DT03677H&imageInfo.ImageIdentifier.Year=2015)
S. Luaces, R. Macías, M. J. Artigas, F. J. Lahoz and L. A. Oro, Dalton Trans., 2015, 44, 5041 DOI: 10.1039/C4DT03677H
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